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Nuwe reaksies van gedeprotoneerde Fischer-tipe karbeenkomplekse
This study comprises the preparation and characterisation of completely new Fischer-type carbene complexes of chromium and tungsten by deprotonation of (CO)5M=C(NMe2)(Me), (CO)5M=C(OMe)(Me) or (CO)5M=C(NMe2)C≡CH, and ...
Metal carboxylate complexes relevant to the Fischer-Tropsch synthesis
(Stellenbosch : Stellenbosch University, 2005-03)
In a Fischer-Tropsch refinery environment carboxylate complexes are of interest since the carboxylic acids present in product streams lead to formation of carboxylate salts through leaching of process equipment and catalysts. ...
Hard-hard and soft-soft coordination in complexes of Group 6 and Group 10 & 11 metals respectively
In this study, the coordination of certain Group 6 and Group 10 & 11 metals to Odonor and S-donor ligands were investigated. For the most part, this involved the isolation of new Mo(VI) and W(VI) complexes. By using a ...