Studies on cobalt(II) complexes with N-thioacylamido(thio)phosphates: X-ray crystal structure of the Co[PhC(S)NP(S)(OPri)2]2
Date
2006
Authors
Safin D.A.
Sokolov F.D.
Zabirov N.G.
Brusko V.V.
Krivolapov D.B.
Litvinov I.A.
Luckay R.C.
Cherkasov R.A.
Journal Title
Journal ISSN
Volume Title
Publisher
Abstract
Reaction of the potassium salts of N-thioacylamidophosphates RC(S)NHP(O)(OPri)2 (R = Ph, PhNH, p-MeOPhNH, p-BrPhNH, iPrNH, tBuNH, Et2N, c-C5H10N, c-OC4H8N, c-C5H11NH) with Co(II) cation in aqueous EtOH leads to the complexes of Co(L-O,S)2 type structure. Complexes Co(B)L2 were obtained by the reaction of chelate complexes CoL2 (R = Ph, PhNH) with 2,2′-bipyridine and 1,10-phenanthroline. Structures of the compounds obtained were investigated by EIMS, IR, UV-Vis spectroscopy and microanalysis. Complex Co[PhC(S)NP(S)(OPri)]2 was investigated by single crystal X-ray diffraction. © 2006 Elsevier Ltd. All rights reserved.
Description
Keywords
Citation
Polyhedron
25
17
25
17