Influence of the metal-to-ligand ratio on the formation of metal organic complexes

Influence of the metal-to-ligand ratio on the formation of metal organic complexes

Dobrzanska L. ; Kleinhans D.J. ; Barbour L.J. ; Dobrzanska L. ; Kleinhans D.J. ; Barbour L.J. (2008)

Article

Article

Three copper(II) salts with a chloride, bromide or nitrate counterions in combination with the ditopic ligand 1,3-bis(imidazol-1-ylmethyl)benzene (L) were used to study the influence of the metal to ligand molar ratio on the formation of the final product. Single-crystal X-ray analysis revealed structural diversity of the products formed, ranging from discrete species to extended 1D and 2D coordination polymers. Similar types of 1D chains were formed for all counterions. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.

Three copper(II) salts with a chloride, bromide or nitrate counterions in combination with the ditopic ligand 1,3-bis(imidazol-1-ylmethyl)benzene (L) were used to study the influence of the metal to ligand molar ratio on the formation of the final product. Single-crystal X-ray analysis revealed structural diversity of the products formed, ranging from discrete species to extended 1D and 2D coordination polymers. Similar types of 1D chains were formed for all counterions. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.

Please refer to this item in SUNScholar by using the following persistent URL: http://hdl.handle.net/10019.1/13039
http://hdl.handle.net/10019.1/13039
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