Lanthanide-induced helical arrays of [{Co(III) sepulchrate} ∩ {p-sulfonatocalix[4]arene}] supermolecules

Smith C.B. ; Barbour L.J. ; Makha M. ; Raston C.L. ; Sobolev A.N. (2006)


In the presence of lanthanide ions, a Co(III) sepulchrate cation [Co(diHOsar)]3+ and sodium p-sulfonatocalix[4]arene form a 1: 1 host-guest complex which is self-assembled into a zeolite-like lattice network comprised of parallel, single stranded helices. © The Royal Society of Chemistry 2006.

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