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Directed reactions within confined reaction environments: Polyadditions in polyelectrolyte-surfactant complexes

dc.contributor.authorGaneva D.
dc.contributor.authorFaul C.F.J.
dc.contributor.authorGotz C.
dc.contributor.authorSanderson R.D.
dc.date.accessioned2011-05-15T15:59:56Z
dc.date.available2011-05-15T15:59:56Z
dc.date.issued2003
dc.identifier.citationMacromolecules
dc.identifier.citation36
dc.identifier.citation8
dc.identifier.issn249297
dc.identifier.other10.1021/ma021136f
dc.identifier.urihttp://hdl.handle.net/10019.1/11445
dc.description.abstractPolyaddition reactions performed within a highly ordered polyelectrolyte-surfactant monomer complex of polydiallyldimethylammonium chloride and di(undecenyl) phosphate give a 1:1 copy of the original lamellar host structure. No phase disruption or disordering occurs during the reaction. The phase morphology of the host before and after swelling and after polymerization is investigated by small-angle-X-ray scattering and transmission electron microscopy. The polymer symplex has an improved thermal and mechanical stability.
dc.subjectAddition reactions
dc.subjectMonomers
dc.subjectPolymerization
dc.subjectSurface active agents
dc.subjectSwelling
dc.subjectThermodynamic stability
dc.subjectTransmission electron microscopy
dc.subjectX ray scattering
dc.subjectPolyaddition
dc.subjectPolyelectrolytes
dc.titleDirected reactions within confined reaction environments: Polyadditions in polyelectrolyte-surfactant complexes
dc.typeArticle
dc.description.versionArticle


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