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Templating polymerization of dodecylammonium surfactants with polymerizable (meth)acrylate counter ions

dc.contributor.authorHartmann P.C.
dc.contributor.authorSanderson R.D.
dc.date.accessioned2011-05-15T15:57:12Z
dc.date.available2011-05-15T15:57:12Z
dc.date.issued2005
dc.identifier.citationMacromolecular Symposia
dc.identifier.citation225
dc.identifier.issn10221360
dc.identifier.other10.1002/masy.200550718
dc.identifier.urihttp://hdl.handle.net/10019.1/10267
dc.description.abstractBoth dodecylammonium acrylate (I) and dodecylammonium methacrylate (II) are reactive surfactants in which the polymerizable group is the organic counterion. Templating polymerization of I and II from the lyotropic liquid crystalline (LLC) lamellar phase was successfully performed with conservation of the supramolecular structure. A 20 wt% aqueous solution of II formed cubic bicontinuous phases, even upon addition of divinyl benzene (DVB). Polymerization from the cubic phases was attempted without and with DVB (3 wt%). Bicontinuous cubic phases always evolved toward lamellar structures upon polymerization. © 2005 International Union of Pure and Applied Chemistry.
dc.subjectCritical micelle concentration
dc.subjectIons
dc.subjectPolymerization
dc.subjectProtons
dc.subjectSelf assembly
dc.subjectSupramolecular chemistry
dc.subjectX ray scattering
dc.subjectCubic phase
dc.subjectDodecylammonium acrylate
dc.subjectLyotropic liquid crystalline (LLC)
dc.subjectTemplates
dc.subjectSurface active agents
dc.titleTemplating polymerization of dodecylammonium surfactants with polymerizable (meth)acrylate counter ions
dc.typeConference Paper
dc.description.versionConference Paper


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